Like I said I've never used the Knu 100% copper, but I would expect performance would be close to identical. If I were ordering 1/0 and ring terminals I'd go through weldingsupply.com, if I were ordering 1/0, RCA's, speaker wire, and other odds and ends I'd probably go with Knu to bundle shipping on other crap I'd need anyway.
One other place to check would be Darvex.com I've found some killer deals on RCA's and assorted cable from them from time to time. They often have blowout prices on older styles of premium brand cable/distro blocks, and other accessories.