its not possible to "double your voltage". just run a set of wires from your existing battery to the new one, in series. then connect your amp to the second battery.
OR, you can run a wire from the positive from the alt, to the battery, then ground the battery to the frame, and the engine block, so therefore, it'll be separate from the other battery. the only downside is you'll be overworking your alt if its anything less then maybe 120 amps