Sorry, you are wrong.
There is no such thing as high-voltage charger, is a 12V charger that provides it nominal current around 2V above the fluctuation voltage of a battery (12.6V). If the charger supply more voltage the battery would excessively heat and damage.
Being a 40A charger, it can provide the 40A at those 14.5V (normally it will have a less than that because this chargers normally use small transformers, but lets assume that is infact 14.5V at 40A)
The amp have a overall eff of 80%, so the input current will pass 250A. The charger will provide 40A and its voltage will drop, because it is his maximum. The voltage wont keep high, the larger the load the less voltage on a power source. Than the batteries will feed the amp (because their voltage wont go down so easily as the charger) AND their voltage will go down because will be flowing 100A each.
If you have any doubt just pick a similar charger, take out the battery of your car, plug the car cables on it and star the engine, and see what happens with its voltage.