That's great! Do you get into arc flash and selective coordination calculations and software also? We use SKM Power Tools.
I agree there are much better quality products available than what the car audio market has available. Much better wire, better fuses, better connectors, etc.
Keep in mind that regardless of the type of wire used, the connection method in a car is limited to the 60 deg. C column in the NEC Ampacity tables. If someone decided to use compression lugs on both ends of the wire, I think the 75 deg C. column could be used.