I will take the time to say this-
When doing the Big whatever, you should know WHY you are doing it rather than just doing it.
So i will explain-
Alt + to Batt +
This gives the current output from the alt more than 1 channel to flow through. This will allow higher voltage to all of it's destinations and is primarily recommended for aftermarket alternators and for stock alternators, minor upgrade in AWG size is recommended. 4awg, for example, is plenty for an addition for this cable.
Batt - to frame\chassis
This is referring to your starting battery.
The reason why this is recommended is because if the + cable coming from your alternator actually did benefit and increased the voltage to the battery slightly, then you will only ever really notice it if you complete the cycle by upgrading the ground as well.
I will say that stock grounds are actually quite sufficient in terms of AWG size, it's just the location sometimes that isn't the best.
But in any event, adding 8-4 AWG wire for ground is plenty of overkill to get this job done for stock alternators. Aftermarket, only 1/0 or larger recommended.
And the last one, pay special attention to how i word this last subject.
ALT Ground to Batt Ground
Notice how i didn't say engine block to frame...
The point of doing this step is as follows-
You increase your ground at your starting battery to benefit when upgrading the + charging cable to the battery.
Well, the alternator needs a perfect cycle too so it's ground should be upgraded as well, not just it's +.
By default, the casing of an alt is ground. Typically, the casing is attached to a Steel bracket using Grade 8 Bolts.
This is attached to the Engine block. The Engine block pretty much barely makes conductive contact with the frame which is where the battery is grounded too.
So, the stock grounding technique for an alternator is terrible and for an aftermarket, dangerously terrible!
So, you do not want to ground your engine block, you want to ground the SOURCE, the alternator itself.
The best way to do this is to ground at the casing itself(without removing any vital bolts), or the bracket that surrounds the alternator or the CLOSEST thing to the alternator and run this ground either directly to the Batt - terminal, the Batt - ground location or straight to chassis with a sanded, clean contact.