When the engine in your car is running, the battery under the hood is drawing around 7A of current.
When the engine in your car is running, the alternator's output will be 14.4v (about) and the battery will be 12.6v. Current flows from high to low. Likewise, when you start your car in the morning your battery is at 12.6v. Turn on your headlights before your crank the engine. Start the car and you'll notice your lights are a bit brighter. You're now running on a higher voltage plateau since the alternator is spinning.
The issue isn't a battery losing voltage or charge quickly, the issue is that batteries are at a lower voltage than a spinning alternator. Adding another battery that's below the alternator's voltage will be another load on the system. This is why good capacitors are not a load; they're at the same voltage.