if you already have your 4ga wiring to the amp, just replace that with 1/0, add a line from your alt to battery, add one from chasis to block and one from neg to chasis.
shouldnt take you more than a couple of hours. You could also complete the big3 with 4ga and leave your existing 4ga in place, If you are going to do it anyway, might as well do all the wire.
in your case
1. try to do big 3.
2. add a second battery
3. last, look into a bigger alt.
if you make it to 2 and add the second batt and it does not do anything, can always return it and go on to the HO alt.