I'm pretty good at getting a glossy finish with using basic black lacquer spray paint and wetsanding...
Step 1 - Round over all the edges with a router, then cover all the cut edges of the mdf with wood filler.
Step 2 - Brush on and entire quart of Miniwax sanding sealer primer.
Step 3 - Sand down that sanding sealer with 400 grit.
Step 4 - Spray on the cheap Rust-Oleum black lacquer spray paint, use 5 cans total, 1 can each coat. Don't waste time westsanding in between coats. I don't and look how good my box came out.
Step 5 - Wetsand the entire box with 2000 grit, then uses some buffing compound on it, then wax with mcquires gold class wax or any other type of polish type wax.
$25 - 5 cans of Rust-Oleum black lacquer spray paint
$12 - 3 packs of 2000 grit sand paper
$12 - 1 quart of Mniwax sanding sealer
$5 - Elmers wood filler
Total cost is only $54 to get a 5-7 cuft box in a black hi-gloss mirror finish as shown above.
Here is the finished shine after wetsanding with 2000 grit...
PM me with your AIM and I can walk you through it step by step. It's best to practice all these steps on a spare piece of mdf 11st before you go all out.