You're vehicle is just like another enclosure.
Think of every install you do like a bandpass.
I don't believe in one single peak frequency.
Best thing to do is test on a termlab the day of a show, do around 3/4 volume, and start around your peak...give about 5 minutes between tests and go up 2 tracks.....5 minutes go up 2 tracks...keep records of every burp. Once you stop gaining go back down 3 tracks and that will get you inbetween the 2 loudest frequencies. Test that...if its quieter then play your loudest frequency.
Humidity, altitude, tempature, sun...how many times you farted in the car can make SPL change from day to day.
Also make sure you change NOTHING inbetween those tests. Seat positions, visor positions, ac vents ANYTHING, be SUPER anal about testing