If the headunit is adding it's own "flavor" to the music, its broken. That is not sound quality. That is what you, as an individual like. If it sounds good to a person, great. But thats not the point when it comes to SQ comps. To the user, their system will always be number one because that person likes it. The point of SQ is to reproduce music as accurate as possible. Nothing should be added or taken away. If a headunit adds "warmth", there goes sound quality because there shouldn't be as much "warmth" from the beginning. Your ears like it, but that isn't the definition of Sound Quality.
Frequency response can be altered through the use of an Equalizer and a crossover.
Before clipping, there are less than 1% THD being put out, thats is impossible to hear with music.
S/N ratio, above 85db (A-weighted), you cannot hear any difference. If you can, I take it that you can hear 45352345 miles away too. Just impossible. 85db is already good, even great. Over road noise, panel resonating, speaker distortion, one in a million that you'll hear a difference in S/N ratio.
DAC convertors, there isn't much importance in that. Different methods to convert, yet end result will be the same. After the conversion, its going straight to the LPF filter anyways. Anyone hear a difference in DAC, you have just won yourself $10,000.
Sounding different and Sound quality are two different things. Most people adjust their system to what they like, but that isn't Sound quality. That is what they like and the whole world doesn't revolve around themselves. Most like to spend excessive amount for the "sound quality", and thats fine. Physco acoustic does wonder.