as your box size decreases your Qtc increases. when you Qtc increases the dampening effect of the box on the woofer decreases, so the woofer has less resistance to fight against it.
also, this higher Q increases the roll off slope of the low end raising your F3.
for instance, take a woofer in a sealed enclosure with a Q of 0.7(ideal for car applications), this will give us a reference peak SPL to base off of. this Qtc wil also yield us a roll off slope of roughly 10.6Db/octave on the low end, yielding an F3 of 35Hz(remember, this is all based on an unspecified woofer)
take that woofer and put it in a box with a Qtc of 0.9 and the results are as follows: .69Db increase in output, 11.95Db/octave roll off, and an F3 of 39Hz.
same woofer with a 1.0 allignment gives: 1.25Db gain in output, 12.08Db/octave roll off, and an F3 of 43Hz
and to illustrate an extreme, the same woofer in a Qtc allignment of 1.5 gives: 4Db increase in output, a 13.96Db/octave slope, and an F3 of 64Hz.
box size is a compromise of several things, as you can see. smaller boxes boost your power handling a bit, and give better SPL output, but they compromise your SQ at the same time. larger boxes are going to sound better, and yield better low end response, but they are going to have slightly diminished output.